The Influence of water and metal salt on the transport and structural properties of 1-Octyl-3-methylimidazolium Chloride Goujon, Nicolas, Byrne, Nolene, Walsh, Tiffany R. and Forsyth, Maria 2015, The Influence of water and metal salt on the transport and structural properties of 1-Octyl-3-methylimidazolium Chloride, Australian journal of chemistry, vol. 68, no. 3, pp. 420-425, doi: 10.1071/CH14240. Attached Files Name Description MIMEType Size Downloads Title The Influence of water and metal salt on the transport and structural properties of 1-Octyl-3-methylimidazolium Chloride Author(s) Goujon, Nicolas Byrne, Nolene orcid.org/0000-0002-9474-7644 Walsh, Tiffany R. orcid.org/0000-0002-0233-9484 Forsyth, Maria orcid.org/0000-0002-4273-8105 Journal name Australian journal of chemistry Volume number 68 Issue number 3 Start page 420 End page 425 Total pages 6 Publisher CSIRO Publishing Place of publication Clayton, Vic. Publication date 2015 ISSN 0004-9425 1445-0038 Keyword(s) Science & Technology Physical Sciences Chemistry, Multidisciplinary Chemistry TEMPERATURE IONIC LIQUID AIR BATTERIES AQUEOUS-SOLUTIONS MIXTURES DYNAMICS SPECTRA NMR SPECTROSCOPY ORGANIZATION AGGREGATION Summary The addition of diluents to ionic liquids (ILs) has recently been shown to enhance the transport properties of ILs. In the context of electrolyte design, this enhancement allows the realisation of IL-based electrolytes for metal-air batteries and other storage devices. It is likely that diluent addition not only impacts the viscosity of the IL, but also the ion-ion interactions and structure. Here, we investigate the nano-structured 1-methyl-3-octylimidazolium chloride (OMImCl) with varying water concentrations in the presence of two metal salts, zinc chloride and magnesium chloride. We find that the choice of metal salt has a significant impact on the structure and transport properties of the system; this is explained by the water structuring and destructing properties of the metal salt. Language eng DOI 10.1071/CH14240 Field of Research 030701 Quantum Chemistry 091205 Functional Materials Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1 Refereed article in a scholarly journal ERA Research output type C Journal article Copyright notice ©2015, CSIRO Publishing Persistent URL http://hdl.handle.net/10536/DRO/DU:30074088 Document type: Journal Article Collections: Institute for Frontier Materials GTP Research Related Links Link Description Connect to published version Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Tue, 30 Jun 2015, 09:04:03 EST Wed, 01 Jul 2015, 05:00:29 EST Wed, 01 Jul 2015, 08:15:28 EST Wed, 06 Apr 2016, 06:22:04 EST Tue, 19 Apr 2016, 11:03:46 EST Filtered Full Citation counts:   Cited 3 times in TR Web of Science Cited 3 times in Scopus Search Google Scholar Access Statistics: 444 Abstract Views, 2 File Downloads  -  Detailed Statistics Created: Tue, 30 Jun 2015, 09:04:03 EST

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