The Influence of water and metal salt on the transport and structural properties of 1-Octyl-3-methylimidazolium Chloride

Goujon, Nicolas, Byrne, Nolene, Walsh, Tiffany R. and Forsyth, Maria 2015, The Influence of water and metal salt on the transport and structural properties of 1-Octyl-3-methylimidazolium Chloride, Australian journal of chemistry, vol. 68, no. 3, pp. 420-425, doi: 10.1071/CH14240.

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Title The Influence of water and metal salt on the transport and structural properties of 1-Octyl-3-methylimidazolium Chloride
Author(s) Goujon, Nicolas
Byrne, Nolene
Walsh, Tiffany R.ORCID iD for Walsh, Tiffany R. orcid.org/0000-0002-0233-9484
Forsyth, MariaORCID iD for Forsyth, Maria orcid.org/0000-0002-4273-8105
Journal name Australian journal of chemistry
Volume number 68
Issue number 3
Start page 420
End page 425
Total pages 6
Publisher CSIRO Publishing
Place of publication Clayton, Vic.
Publication date 2015
ISSN 0004-9425
1445-0038
Keyword(s) Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Chemistry
TEMPERATURE IONIC LIQUID
AIR BATTERIES
AQUEOUS-SOLUTIONS
MIXTURES
DYNAMICS
SPECTRA
NMR
SPECTROSCOPY
ORGANIZATION
AGGREGATION
Summary The addition of diluents to ionic liquids (ILs) has recently been shown to enhance the transport properties of ILs. In the context of electrolyte design, this enhancement allows the realisation of IL-based electrolytes for metal-air batteries and other storage devices. It is likely that diluent addition not only impacts the viscosity of the IL, but also the ion-ion interactions and structure. Here, we investigate the nano-structured 1-methyl-3-octylimidazolium chloride (OMImCl) with varying water concentrations in the presence of two metal salts, zinc chloride and magnesium chloride. We find that the choice of metal salt has a significant impact on the structure and transport properties of the system; this is explained by the water structuring and destructing properties of the metal salt.
Language eng
DOI 10.1071/CH14240
Field of Research 030701 Quantum Chemistry
091205 Functional Materials
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
ERA Research output type C Journal article
Copyright notice ©2015, CSIRO Publishing
Persistent URL http://hdl.handle.net/10536/DRO/DU:30074088

Document type: Journal Article
Collection: Institute for Frontier Materials
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