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On the use of 'shortcuts' in the method of continuous variation (Job's method)

Long, Benjamin M. and Pfeffer, Frederick M. 2015, On the use of 'shortcuts' in the method of continuous variation (Job's method), Supramolecular chemistry, vol. 27, no. 1-2, pp. 136-140, doi: 10.1080/10610278.2014.909044.

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Title On the use of 'shortcuts' in the method of continuous variation (Job's method)
Author(s) Long, Benjamin M.ORCID iD for Long, Benjamin M. orcid.org/0000-0002-3248-8851
Pfeffer, Frederick M.ORCID iD for Pfeffer, Frederick M. orcid.org/0000-0002-5441-6437
Journal name Supramolecular chemistry
Volume number 27
Issue number 1-2
Start page 136
End page 140
Total pages 5
Publisher Taylor & Francis
Place of publication London, Eng.
Publication date 2015
ISSN 1061-0278
1029-0478
Keyword(s) anion recognition
host-guest
Job plot
Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Chemistry
ASSOCIATION CONSTANTS
BINDING CONSTANTS
COMPLEXES
HOSTS
STABILITY
FLUORIDE
WATER
BIS
SPECTROSCOPY
Summary The use of modified Job plot methodology provides a quick and easy means for evaluating host-guest stoichiometry and requires less material than the original method. In this short paper, the results of a recent anion recognition study using thiourea-functionalised norbornanes and [n]polynorbornanes are presented. A significant difference between the plots constructed using the original and modified method was observed and, as such, caution is advised when the modified Job's method is solely used for the determination of host-guest stoichiometry.
Language eng
DOI 10.1080/10610278.2014.909044
Field of Research 030302 Nanochemistry and Supramolecular Chemistry
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
ERA Research output type C Journal article
Grant ID ARC DP 140100227
Copyright notice ©2014, Taylor & Francis
Persistent URL http://hdl.handle.net/10536/DRO/DU:30076218

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Created: Fri, 27 Nov 2015, 10:05:14 EST

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