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Crystalline polymorph transition in poly(vinylidene fluoride) (PVDF)/acrylic rubber(ACM)/clay partially miscible hybrid

Abolhasani, Mohammad Mahdi, Fashandi, Hossein and Naebe, Minoo 2016, Crystalline polymorph transition in poly(vinylidene fluoride) (PVDF)/acrylic rubber(ACM)/clay partially miscible hybrid, Polymer bulletin, vol. 73, no. 1, pp. 65-73, doi: 10.1007/s00289-015-1472-7.

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Title Crystalline polymorph transition in poly(vinylidene fluoride) (PVDF)/acrylic rubber(ACM)/clay partially miscible hybrid
Author(s) Abolhasani, Mohammad Mahdi
Fashandi, Hossein
Naebe, Minoo
Journal name Polymer bulletin
Volume number 73
Issue number 1
Start page 65
End page 73
Total pages 9
Publisher Springer
Place of publication New York, N.Y.
Publication date 2016-01
ISSN 0170-0839
Keyword(s) Science & Technology
Physical Sciences
Polymer Science
Nanocomposite
Partial miscibility
Conjugated phases
Polymorph
FERROELECTRIC PROPERTIES
PVDF NANOCOMPOSITES
THERMAL-DEGRADATION
MELT INTERCALATION
MODIFIED SILICATE
POLYMER BLEND
BEHAVIOR
FTIR
FILMS
Summary This study investigates the intercalation of nanoclay in partially miscible blends of poly(vinylidene fluoride) (PVDF) and acrylic rubber(ACM). Transmission electron microscopy and X-ray diffraction technique were used to investigate the formation of nanoscale polymer blend/clay hybrids. Using Infrared spectroscopy and X-ray analysis, the different polymorph formation in PVDF nanocomposite and conjugated phases of partially miscible nanocomposite was studied. Nanoclay was found to induce β and γ polymorphs while ACM tend to induce α phase in this polymer system. It was shown that PVDF chains in ACM-rich phase of partially miscible nanocomposites interact with ACM chains which in return form α polymorph in the presence of ACM. Further observations revealed that nanoclay in α polymorph is wrapped by ACM molecules.
Language eng
DOI 10.1007/s00289-015-1472-7
Field of Research 091299 Materials Engineering not elsewhere classified
0303 Macromolecular And Materials Chemistry
0912 Materials Engineering
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
ERA Research output type C Journal article
Copyright notice ©2016, Springer
Persistent URL http://hdl.handle.net/10536/DRO/DU:30076646

Document type: Journal Article
Collection: Institute for Frontier Materials
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