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Different complexation behavior of P-functionalized ferrocene derivatives towards SnCl2 , SnCl4 and SnPh2 Cl2 : auto-ionization and redox-type reactions

Gawron, Matthias, Dietz, Christina, Lutter, Michael, Duthie, Andrew, Jouikov, Viatcheslav and Jurkschat, Klaus 2015, Different complexation behavior of P-functionalized ferrocene derivatives towards SnCl2 , SnCl4 and SnPh2 Cl2 : auto-ionization and redox-type reactions, Chemistry : a European journal, vol. 21, no. 46, pp. 16609-16622, doi: 10.1002/chem.201501999.

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Title Different complexation behavior of P-functionalized ferrocene derivatives towards SnCl2 , SnCl4 and SnPh2 Cl2 : auto-ionization and redox-type reactions
Author(s) Gawron, Matthias
Dietz, Christina
Lutter, Michael
Duthie, Andrew
Jouikov, Viatcheslav
Jurkschat, Klaus
Journal name Chemistry : a European journal
Volume number 21
Issue number 46
Start page 16609
End page 16622
Total pages 14
Publisher Wiley
Place of publication Weinheim, Germany
Publication date 2015-11-09
ISSN 0947-6539
1521-3765
Keyword(s) x-ray diffraction
density functional calculations
ferrocene
phosphorus
tin
Summary The novel phosphonyl-substituted ferrocene derivatives [Fe(η(5) -Cp)(η(5) -C5 H3 {P(O)(O-iPr)2 }2 -1,2)] (Fc(1,2) ) and [Fe{η(5) -C5 H4 P(O)(O-iPr)2 }2 ] (Fc(1,1') ) react with SnCl2 , SnCl4 , and SnPh2 Cl2 , giving the corresponding complexes [(Fc(1,2) )2 SnCl][SnCl3 ] (1), [{(Fc(1,1') )SnCl2 }n ] (2), [(Fc(1,1') )SnCl4 ] (3), [{(Fc(1,1') )SnPh2 Cl2 }n ] (4), and [(Fc(1,2) )SnCl4 ] (5), respectively. The compounds are characterized by elemental analyses, (1) H, (13) C, (31) P, (119) Sn NMR and IR spectroscopy, (31) P and (119) Sn CP-MAS NMR spectroscopy, cyclovoltammetry, electrospray ionization mass spectrometry, and single-crystal as well as powder X-ray diffraction analyses. The experimental work is accompanied by DFT calculations, which help to shed light on the origin for the different reaction behavior of Fc(1,1') and Fc(1,2) towards tin(II) chloride.
Language eng
DOI 10.1002/chem.201501999
Field of Research 039904 Organometallic Chemistry
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
ERA Research output type C Journal article
Copyright notice ©2015, Wiley
Persistent URL http://hdl.handle.net/10536/DRO/DU:30080912

Document type: Journal Article
Collection: School of Life and Environmental Sciences
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