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Analytically useful blue chemiluminescence from a water-soluble iridium(iii) complex containing a tetraethylene glycol functionalised triazolylpyridine ligand

Smith, Zoe M., Kerr, Emily, Doeven, Egan H., Connell, Timothy U., Barnett, Neil W., Donnelly, Paul S., Haswell, Stephen J. and Francis, Paul S. 2016, Analytically useful blue chemiluminescence from a water-soluble iridium(iii) complex containing a tetraethylene glycol functionalised triazolylpyridine ligand, Analyst, vol. 141, no. 7, pp. 2140-2144, doi: 10.1039/c6an00141f.

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Title Analytically useful blue chemiluminescence from a water-soluble iridium(iii) complex containing a tetraethylene glycol functionalised triazolylpyridine ligand
Author(s) Smith, Zoe M.
Kerr, Emily
Doeven, Egan H.
Connell, Timothy U.
Barnett, Neil W.
Donnelly, Paul S.
Haswell, Stephen J.
Francis, Paul S.ORCID iD for Francis, Paul S. orcid.org/0000-0003-4165-6922
Journal name Analyst
Volume number 141
Issue number 7
Start page 2140
End page 2144
Total pages 5
Publisher Royal Society of Chemistry
Place of publication London, Eng.
Publication date 2016-04-07
ISSN 1364-5528
Keyword(s) Science & Technology
Physical Sciences
Chemistry, Analytical
Chemistry
ELECTROGENERATED CHEMILUMINESCENCE
SELECTIVE EXCITATION
EMISSION COLOR
EXCITED-STATES
ELECTROCHEMILUMINESCENCE
SYSTEMS
GREEN
PHENYLPYRIDINE
PHOSPHORESCENT
OFLOXACIN
Summary We examine [Ir(df-ppy)2(pt-TEG)](+) as the first highly water soluble, blue-luminescent iridium(iii) complex for chemiluminescence detection. Marked differences in selectivity were observed between the new complex and the conventional [Ru(bpy)3](2+) reagent, which will enable this mode of detection to be extended to new areas of application.
Language eng
DOI 10.1039/c6an00141f
Field of Research 030101 Analytical Spectrometry
030103 Flow Analysis
030207 Transition Metal Chemistry
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
ERA Research output type C Journal article
Grant ID DP140100439
FT100100646
Copyright notice ©2016, RSC
Persistent URL http://hdl.handle.net/10536/DRO/DU:30083075

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