Competition between cluster fragmentation, C–C bond coupling and C–X bond activation in silver hexynyl cluster cations, [(C4H9CCAg)nAg]+. Size does matter!
Wang, Farrah Qiuyun, Khairallah, George N., Koutsantonis, George A., Williams, Craig M., Callahan, Damien L. and O’Hair, Richard A.J. 2009, Competition between cluster fragmentation, C–C bond coupling and C–X bond activation in silver hexynyl cluster cations, [(C4H9CCAg)nAg]+. Size does matter!, Physical chemistry chemical physics, vol. 11, no. 21, Article Number : 4132, pp. 1-4, doi: 10.1039/b904687a.
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Title
Competition between cluster fragmentation, C–C bond coupling and C–X bond activation in silver hexynyl cluster cations, [(C4H9CCAg)nAg]+. Size does matter!
Silver hexynyl cluster cations, [(C4H9CCAg)nAg]+, exhibit a rich unimolecular chemistry that is dependant on the cluster size, n (1–5), cluster fragmentation (for all n > 1); C–C bond coupling (n = 3 & 4); C–H bond activation with comcomitant silver hydride formation (n = 1 & 4); C–C bond activation (n = 1 & 4).
Language
eng
DOI
10.1039/b904687a
Field of Research
030108 Separation Science 03 Chemical Sciences
Socio Economic Objective
970103 Expanding Knowledge in the Chemical Sciences
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