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Using steric bulk for selective recognition; blocking the binding site to differentiate guests

Robson, Ryan N. and Pfeffer, Frederick M. 2016, Using steric bulk for selective recognition; blocking the binding site to differentiate guests, Chemical communications, vol. 52, no. 56, pp. 8719-8721, doi: 10.1039/c6cc04549a.

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Title Using steric bulk for selective recognition; blocking the binding site to differentiate guests
Author(s) Robson, Ryan N.
Pfeffer, Frederick M.ORCID iD for Pfeffer, Frederick M. orcid.org/0000-0002-5441-6437
Journal name Chemical communications
Volume number 52
Issue number 56
Start page 8719
End page 8721
Total pages 3
Publisher Royal Society of Chemistry
Place of publication Cambridge, Eng.
Publication date 2016
ISSN 1364-548X
Keyword(s) Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Chemistry
ANION RECOGNITION
MOLECULAR HOSTS
LIGAND-BINDING
RECEPTORS
9,10-DIHYDROFULVALENE
COMPLEXES
CYCLOADDITION
DERIVATIVES
FRAMEWORKS
DESIGN
Summary Selectivity is demonstrated in a supramolecular host:guest system using a receptor with a non-linear binding site. For the "open" receptor 1 strong binding for both flexible and rigid guests was observed. Receptor 2, with a "blocked" binding site, also bound flexible guests effectively but its affinity for rigid guests was 50 fold lower.
Language eng
DOI 10.1039/c6cc04549a
Field of Research 030302 Nanochemistry and Supramolecular Chemistry
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
ERA Research output type C Journal article
Grant ID DP140100227
Copyright notice ©2016, Royal Society of Chemistry
Free to Read? Yes
Use Rights Creative Commons Attribution licence
Persistent URL http://hdl.handle.net/10536/DRO/DU:30085154

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Every reasonable effort has been made to ensure that permission has been obtained for items included in DRO. If you believe that your rights have been infringed by this repository, please contact drosupport@deakin.edu.au.