Cobalt carbonate hydroxide nanowire array on ti mesh: an efficient and robust 3D catalyst for on-demand hydrogen generation from alkaline naBH4 solution. Cui, Liang, Sun, Xuping, Xu, Yuanhong, Yang, Wenrong and Liu, Jingquan 2016, Cobalt carbonate hydroxide nanowire array on ti mesh: an efficient and robust 3D catalyst for on-demand hydrogen generation from alkaline naBH4 solution., Chemistry: a European journal, vol. 22, no. 42, pp. 14831-14835, doi: 10.1002/chem.201603087. Attached Files Name Description MIMEType Size Downloads Title Cobalt carbonate hydroxide nanowire array on ti mesh: an efficient and robust 3D catalyst for on-demand hydrogen generation from alkaline naBH4 solution. Author(s) Cui, Liang Sun, Xuping Xu, Yuanhong Yang, Wenrong orcid.org/0000-0001-8815-1951 Liu, Jingquan Journal name Chemistry: a European journal Volume number 22 Issue number 42 Start page 14831 End page 14835 Total pages 5 Publisher Wiley Place of publication Chichester, Eng. Publication date 2016-08-11 ISSN 1521-3765 1521-3765 Keyword(s) cobalt carbonate hydroxide on-demand hydrogen generation self-supported catalyst sodium borohydride Summary In this work, for the first time, a cobalt carbonate hydroxide (Co(CO3 )0.5 (OH)⋅0.11 H2 O) nanowire array on Ti mesh (CHNA/Ti) was applied to drive the dehydrogenation of alkaline NaBH4 solution for on-demand hydrogen production. Compared with other nanostructured Co-based catalyst systems, CHNA/Ti can be activated more quickly and separated easily from fuel solutions. This self-supported cobalt salt nanowire array catalyst works as an efficient and robust 3D catalyst for the hydrolysis reaction of NaBH4 with a hydrogen generation rate of 4000 mL min(-1)  gCo (-1) and a low apparent activation energy of 39.78 kJ mol(-1) and offers an attractive system for on-demand hydrogen generation. Language eng DOI 10.1002/chem.201603087 Field of Research 030302 Nanochemistry and Supramolecular Chemistry Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1 Refereed article in a scholarly journal ERA Research output type C Journal article Copyright notice ©2016, Wiley Persistent URL http://hdl.handle.net/10536/DRO/DU:30086238 Document type: Journal Article Collections: Faculty of Science, Engineering and Built Environment School of Life and Environmental Sciences Related Links Link Description Connect to published version Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Thu, 22 Sep 2016, 13:43:18 EST Tue, 15 Nov 2016, 13:13:42 EST Wed, 16 Nov 2016, 04:00:31 EST Wed, 16 Nov 2016, 05:08:39 EST Fri, 18 Nov 2016, 15:04:19 EST Fri, 18 Nov 2016, 15:05:23 EST Tue, 13 Feb 2018, 15:10:00 EST Tue, 13 Feb 2018, 15:10:50 EST Filtered Full Citation counts:   Cited 12 times in TR Web of Science Cited 12 times in Scopus Search Google Scholar Access Statistics: 411 Abstract Views, 4 File Downloads  -  Detailed Statistics Created: Tue, 15 Nov 2016, 13:13:42 EST

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