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Hydrothermal synthesis of dioctahedral smectites: The Al-Fe3+chemical series. Part II: crystal-chemistry

Petit, S., Decarreau, A., Gates, W., Andrieux, P. and Grauby, O. 2015, Hydrothermal synthesis of dioctahedral smectites: The Al-Fe3+chemical series. Part II: crystal-chemistry, Applied clay science, vol. 104, pp. 96-105, doi: 10.1016/j.clay.2014.11.014.

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Title Hydrothermal synthesis of dioctahedral smectites: The Al-Fe3+chemical series. Part II: crystal-chemistry
Author(s) Petit, S.
Decarreau, A.
Gates, W.ORCID iD for Gates, W. orcid.org/0000-0001-7388-0289
Andrieux, P.
Grauby, O.
Journal name Applied clay science
Volume number 104
Start page 96
End page 105
Total pages 10
Publisher Elsevier
Place of publication Amsterdam, The Netherlands
Publication date 2015-02
ISSN 0169-1317
Summary The crystal-chemistry of a series of synthetic Al-Fe3+ smectites was studied in detail using near and mid infrared spectroscopy. Chemical and NIR data indicated a quite complete range of octahedral Al for Fe3+ substitution, and therefore, the solid-solution between beidellite and nontronite end-members was continuous and complete. The wavenumbers of several infrared absorption bands were correlated with the chemistry of the synthetic smectites, providing a useful tool to constrain their structural formulae and also for assisting in assignments of similar bands in natural smectites. The Al and Fe3+ cations were shown to be randomly distributed in the octahedral sheet of synthesized smectites. Despite the high availability of iron during synthesis, generally only a small amount of tetrahedral Fe3+ was observed.
Language eng
DOI 10.1016/j.clay.2014.11.014
Field of Research 040306 Mineralogy and Crystallography
Socio Economic Objective 970104 Expanding Knowledge in the Earth Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
ERA Research output type C Journal article
Copyright notice ©2014, Elsevier B.V.
Persistent URL http://hdl.handle.net/10536/DRO/DU:30086973

Document type: Journal Article
Collection: Institute for Frontier Materials
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