You are not logged in.

Synthesis, structure and spectral properties of dithiocarbamato bridged dirhenium(III,II) complexes: a combined experimental and theoretical study

Mallick, Suman, Ghosh, Mrinal Kanti, Mohapatra, Manoj, Mohapatra, Sudip and Chattopadhyay, Swarup 2015, Synthesis, structure and spectral properties of dithiocarbamato bridged dirhenium(III,II) complexes: a combined experimental and theoretical study, Inorganica chimica acta, vol. 424, Special issue: Metal-metal bonded compounds, pp. 129-135, doi: 10.1016/j.ica.2014.07.047.

Attached Files
Name Description MIMEType Size Downloads

Title Synthesis, structure and spectral properties of dithiocarbamato bridged dirhenium(III,II) complexes: a combined experimental and theoretical study
Author(s) Mallick, Suman
Ghosh, Mrinal Kanti
Mohapatra, Manoj
Mohapatra, Sudip
Chattopadhyay, Swarup
Journal name Inorganica chimica acta
Volume number 424
Season Special issue: Metal-metal bonded compounds
Start page 129
End page 135
Total pages 7
Publisher Elsevier
Place of publication Amsterdam, The Netherlands
Publication date 2015-01-01
ISSN 0020-1693
1873-3255
Keyword(s) dirhenium(III,II)
dithiocarbamate
paramagnetic
edge-shared bioctahedra
density functional theory
Summary Sodium salts of dimethyldithiocarbamate, diethyldithiocarbamate and pyrrolidinedithiocarbamate react with the multiply bonded paramagnetic dirhenium(III,II) complex Re2(μ-O2CCH3)Cl4(μ-dppm)2, 1 (dppm = Ph2PCH2PPh2) in refluxing ethanol to afford the paramagnetic substitution products of the type Re2(η2-S,S)2(μ-S,S)(μ-Cl)2(μ-dppm), where S,S represents the dithiocarbamato ligands [S,S = S2CNMe2, 4(LMe); S2CNEt2, 4(LEt) and S2CN(CH2)4, 4(LPyr)]. These are the first examples of dirhenium complexes that contain bridging dithiocarbamato ligand along with the dppm ligand. These complexes have very similar spectral (UV-Vis, IR, EPR) and electrochemical properties which are also reported. The identity of 4(LEt) has been established by single-crystal X-ray structure determination (Re-Re distance 2.6385 (9) Å) and is shown to have edge-shared bioctahedral structure. The electronic structure and the absorption spectra of the complexes are scrutinized by the density functional theory (DFT) and time-dependent density functional theory (TD-DFT) analyses.
Language eng
DOI 10.1016/j.ica.2014.07.047
Field of Research 030299 Inorganic Chemistry not elsewhere classified
030199 Analytical Chemistry not elsewhere classified
0302 Inorganic Chemistry
0399 Other Chemical Sciences
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
ERA Research output type C Journal article
Copyright notice ©2014, Elsevier
Persistent URL http://hdl.handle.net/10536/DRO/DU:30088564

Document type: Journal Article
Collection: School of Life and Environmental Sciences
Connect to link resolver
 
Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved.

Versions
Version Filter Type
Citation counts: TR Web of Science Citation Count  Cited 0 times in TR Web of Science
Scopus Citation Count Cited 2 times in Scopus
Google Scholar Search Google Scholar
Access Statistics: 44 Abstract Views, 0 File Downloads  -  Detailed Statistics
Created: Mon, 07 Nov 2016, 13:11:31 EST

Every reasonable effort has been made to ensure that permission has been obtained for items included in DRO. If you believe that your rights have been infringed by this repository, please contact drosupport@deakin.edu.au.