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Heteronuclear tin(IV)-silver(I) complexes with phosphinothiolate ligands. X-ray structure of [AgSn (μSC₆H₄PPh₂) ₂Me₂ (PPhMe₂)] CF₃SO₃·CH₂Cl₂

Aznar, Jesus, Cerrada, Elena, Hursthouse, Michael B., Laguna, Mariano, Pozo, Cristina and Romero, M. Pilar 2001, Heteronuclear tin(IV)-silver(I) complexes with phosphinothiolate ligands. X-ray structure of [AgSn (μSC₆H₄PPh₂) ₂Me₂ (PPhMe₂)] CF₃SO₃·CH₂Cl₂, Journal of organometallic chemistry, vol. 622, no. 1-2, pp. 274-279, doi: 10.1016/S0022-328X(00)00936-0.

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Title Heteronuclear tin(IV)-silver(I) complexes with phosphinothiolate ligands. X-ray structure of [AgSn (μSC₆H₄PPh₂) ₂Me₂ (PPhMe₂)] CF₃SO₃·CH₂Cl₂
Author(s) Aznar, Jesus
Cerrada, Elena
Hursthouse, Michael B.
Laguna, Mariano
Pozo, CristinaORCID iD for Pozo, Cristina orcid.org/0000-0002-7890-6457
Romero, M. Pilar
Journal name Journal of organometallic chemistry
Volume number 622
Issue number 1-2
Start page 274
End page 279
Total pages 6
Publisher Elsevier
Place of publication Amsterdam, The Netherlands
Publication date 2001-03-09
ISSN 0022-328X
Keyword(s) tin
silver
phosphinethiolate
heteronuclear derivatives
Summary [SnR 2 (SC 6 H 4 PPh 2 ) 2 ] (R=Me or Ph) react with silver complexes such as [Ag(CF 3 SO 3 )(PR 3 )] (PR 3 =PPh 3 and PPh 2 Me) to give [AgSn(μ-SC 6 H 4 PPh 2 ) 2 R 2 (PR 3 )]CF 3 SO 3 (1-4) where silver atom are coordinated to the PPh 2 group of the phosphinethiolate ligand as confirmed in the X-ray crystal structure of [AgSn(μ-SC 6 H 4 PPh 2 ) 2 Me 2 (PPh 2 Me)]CF 3 SO 3 ·CH 2 Cl 2 (2). Similar tin derivatives [SnR 2 {(SC 6 H 4 ) 2 PPh}] (R=Me, 5; R=Ph, 6) where synthesised and reacted with [Ag(CF 3 SO 3 )(PR 3 )] and [Ag(CF 3 SO 3 )] to give in both cases [AgSn{μ-(C 6 H 4 ) 2 PPh}R 2 ]CF 3 SO 3 (R=Me, 7; R=Ph, 8)
Language eng
DOI 10.1016/S0022-328X(00)00936-0
Field of Research 0302 Inorganic Chemistry
0305 Organic Chemistry
0399 Other Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2001, Elsevier
Persistent URL http://hdl.handle.net/10536/DRO/DU:30099853

Document type: Journal Article
Collection: Institute for Frontier Materials
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