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An efficient route for electrooxidation of methanol to dimethoxymethane using ionic liquid as electrolyte

Li, Ying, Wang, Hongmei, Wang, Hongxia, Lu, Bin, Zhao, Jingxiang and Cai, Qinghai 2017, An efficient route for electrooxidation of methanol to dimethoxymethane using ionic liquid as electrolyte, Journal of the Electrochemical Society, vol. 164, no. 8, pp. H5074-H5077, doi: 10.1149/2.0111708jes.

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Title An efficient route for electrooxidation of methanol to dimethoxymethane using ionic liquid as electrolyte
Author(s) Li, Ying
Wang, Hongmei
Wang, Hongxia
Lu, Bin
Zhao, Jingxiang
Cai, Qinghai
Journal name Journal of the Electrochemical Society
Volume number 164
Issue number 8
Start page H5074
End page H5077
Total pages 4
Publisher ECS
Place of publication New York, N.Y.
Publication date 2017-01-01
ISSN 0013-4651
1945-7111
Summary An ionic liquid 1-ethyl-3-methyl imidazolium tetrafloroborate (EmimBF4) was found to be highly active for one-pot synthesis of dimethoxymethane (DMM) by electrooxidation of methanol on platinum electrode, exhibiting 34.7% conversion, 96.9% selectivity to DMM, high current efficiency (99.2%) as well. The electrode reaction mechanism was proposed according to the experimental results and reported literature.
Language eng
DOI 10.1149/2.0111708jes
Field of Research 0303 Macromolecular And Materials Chemistry
0306 Physical Chemistry (Incl. Structural)
0912 Materials Engineering
HERDC Research category C1 Refereed article in a scholarly journal
Copyright notice ©2017, The Authors
Free to Read? Yes
Use Rights Creative Commons Attribution licence
Persistent URL http://hdl.handle.net/10536/DRO/DU:30111416

Document type: Journal Article
Collections: Institute for Frontier Materials
Open Access Collection
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Every reasonable effort has been made to ensure that permission has been obtained for items included in DRO. If you believe that your rights have been infringed by this repository, please contact drosupport@deakin.edu.au.