Poly(ionic liquid) iongel membranes for all solid-state rechargeable sodium battery Fdz De Anastro, A, Lago, N, Berlanga, C, Galcerán, M, Hilder, Matthias, Forsyth, Maria and Mecerreyes, D 2019, Poly(ionic liquid) iongel membranes for all solid-state rechargeable sodium battery, Journal of Membrane Science, vol. 582, pp. 435-441, doi: 10.1016/j.memsci.2019.02.074. Attached Files Name Description MIMEType Size Downloads Title Poly(ionic liquid) iongel membranes for all solid-state rechargeable sodium battery Author(s) Fdz De Anastro, A Lago, N Berlanga, C Galcerán, M Hilder, Matthias orcid.org/0000-0002-1649-3546 Forsyth, Maria orcid.org/0000-0002-4273-8105 Mecerreyes, D Journal name Journal of Membrane Science Volume number 582 Start page 435 End page 441 Total pages 7 Publisher Elsevier Place of publication Amsterdam, The Netherlands Publication date 2019-07-15 ISSN 0376-7388 1873-3123 Keyword(s) Ionic liquid membranes Polymer electrolytes Sodium-ion batteries Science & Technology Technology Physical Sciences Engineering, Chemical Polymer Science Engineering IONIC-CONDUCTIVITY Summary Sodium-ion is seen as one of the most promising alternative technologies to the current lithium-ion batteries. Sodium is cheap and widely available in comparison to lithium, however new electrode and polymer electrolyte materials need to be found to improve the performance and security of sodium batteries. In this work, we show a new iongel electrolyte with excellent properties for an all solid-state rechargeable sodium batteries. This iongel membrane is based on the poly(dimethyldiallylammonium)polyDADMA-TFSI poly(ionic liquid), N-Propyl-N-methylpyrrolidinium bis(fluorosulfonyl)imide (C3mpyrFSI)and sodium bis (fluorosulfonyl)imide (NaFSI)the salt. PolyDADMA-TFSI can incorporate up to 50 wt% of C3mpyrFSI ionic liquid content in a self-standing membrane with high ionic conductivity. The increasing the NaFSI concentration in this electrolyte was beneficial for the sodium transference number but detrimental for the ionic conductivity of the membranes. The addition of alumina nanoparticles further improved the membrane mechanical robustness without affecting significantly the ionic conductivity. The iongel membranes presented a wide electrochemical window of 5 V thereby supporting sodium electrochemistry as demonstrated by excellent symmetric sodium cell cycling at 70 ᵒC for 60 cycles. Finally, the electrochemical performance of the optimum composition iongel was evaluated in sodium all solid-state battery using a sodium metal anode and NaFePO4 as the cathode material. The cells show good capacity retention with high coulombic efficiency (>97%)at C rates between C/20 and C/5 achieving 110 mAhg−1 at C/20. Language eng DOI 10.1016/j.memsci.2019.02.074 Field of Research 091205 Functional Materials 030604 Electrochemistry 030399 Macromolecular and Materials Chemistry not elsewhere classified 03 Chemical Sciences 09 Engineering Socio Economic Objective 850602 Energy Storage (excl. Hydrogen) HERDC Research category C1 Refereed article in a scholarly journal Grant ID CE140100012 DP160101178 Copyright notice ©2019, Elsevier B.V. Persistent URL http://hdl.handle.net/10536/DRO/DU:30121926 Document type: Journal Article Collections: Institute for Frontier Materials GTP Research Related Links Link Description Connect to published version (restricted access) Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Fri, 17 May 2019, 14:37:29 EST Sat, 18 May 2019, 05:06:16 EST Mon, 20 May 2019, 08:25:57 EST Sat, 01 Jun 2019, 02:30:58 EST Fri, 11 Oct 2019, 14:04:06 EST Fri, 18 Oct 2019, 15:03:21 EST Fri, 18 Oct 2019, 15:07:00 EST Mon, 21 Oct 2019, 07:50:30 EST Filtered Full Citation counts:   Cited 8 times in TR Web of Science Cited 19 times in Scopus Search Google Scholar Access Statistics: 181 Abstract Views, 0 File Downloads  -  Detailed Statistics Created: Fri, 17 May 2019, 14:37:29 EST

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