Cathodic electrogenerated chemiluminescence of tris(2,2′-bipyridine)ruthenium(ii) and peroxydisulfate at pure Ti3C2Tx MXene electrodes

Zhang, Jizhen, Kerr, Emily, Usman, Ken Aldren S., Doeven, Egan H., Francis, Paul S., Henderson, Luke C. and Razal, Joselito M. 2020, Cathodic electrogenerated chemiluminescence of tris(2,2′-bipyridine)ruthenium(ii) and peroxydisulfate at pure Ti3C2Tx MXene electrodes, Chemical communications (Cambridge, England), vol. 56, no. 69, pp. 10022-10025, doi: 10.1039/d0cc02993a.

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Title Cathodic electrogenerated chemiluminescence of tris(2,2′-bipyridine)ruthenium(ii) and peroxydisulfate at pure Ti3C2Tx MXene electrodes
Formatted title Cathodic electrogenerated chemiluminescence of tris(2,2′-bipyridine)ruthenium(ii) and peroxydisulfate at pure Ti3C2Tx MXene electrodes
Author(s) Zhang, Jizhen
Kerr, Emily
Usman, Ken Aldren S.ORCID iD for Usman, Ken Aldren S. orcid.org/0000-0001-7102-6847
Doeven, Egan H.ORCID iD for Doeven, Egan H. orcid.org/0000-0003-2677-4269
Francis, Paul S.ORCID iD for Francis, Paul S. orcid.org/0000-0003-4165-6922
Henderson, Luke C.ORCID iD for Henderson, Luke C. orcid.org/0000-0002-4244-2056
Razal, Joselito M.ORCID iD for Razal, Joselito M. orcid.org/0000-0002-9758-3702
Journal name Chemical communications (Cambridge, England)
Volume number 56
Issue number 69
Start page 10022
End page 10025
Total pages 4
Publisher Royal Society of Chemistry
Place of publication London, Eng.
Publication date 2020-09-07
ISSN 1359-7345
1364-548X
Summary We demonstrate the first use of pure films of two-dimensional (2D) transition metal carbides and nitrides (Ti3C2Tx MXene) as an electrode material for electrogenerated chemiluminescence (ECL). The Ti3C2Tx MXene electrodes exhibited excellent electrochemical stability in the cathodic scan range and produced bright reductive–oxidation ECL using peroxydisulfate as a co-reactant with the tris(2,2′-bipyridine)ruthenium(II) ([Ru(bpy)3]2+) luminophore.
Language eng
DOI 10.1039/d0cc02993a
Indigenous content off
Field of Research 03 Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
Copyright notice ©2020, The Royal Society of Chemistry
Persistent URL http://hdl.handle.net/10536/DRO/DU:30141145

Document type: Journal Article
Collections: Institute for Frontier Materials
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