Cathodic electrogenerated chemiluminescence of tris(2,2′-bipyridine)ruthenium(ii) and peroxydisulfate at pure Ti3C2Tx MXene electrodes
Zhang, Jizhen, Kerr, Emily, Usman, Ken Aldren S., Doeven, Egan H., Francis, Paul S., Henderson, Luke C. and Razal, Joselito M. 2020, Cathodic electrogenerated chemiluminescence of tris(2,2′-bipyridine)ruthenium(ii) and peroxydisulfate at pure Ti3C2Tx MXene electrodes, Chemical communications (Cambridge, England), vol. 56, no. 69, pp. 10022-10025, doi: 10.1039/d0cc02993a.
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Title
Cathodic electrogenerated chemiluminescence of tris(2,2′-bipyridine)ruthenium(ii) and peroxydisulfate at pure Ti3C2Tx MXene electrodes
Formatted title
Cathodic electrogenerated chemiluminescence of tris(2,2′-bipyridine)ruthenium(ii) and peroxydisulfate at pure Ti3C2Tx MXene electrodes
We demonstrate the first use of pure films of two-dimensional (2D) transition metal carbides and nitrides (Ti3C2Tx MXene) as an electrode material for electrogenerated chemiluminescence (ECL). The Ti3C2Tx MXene electrodes exhibited excellent electrochemical stability in the cathodic scan range and produced bright reductive–oxidation ECL using peroxydisulfate as a co-reactant with the tris(2,2′-bipyridine)ruthenium(II) ([Ru(bpy)3]2+) luminophore.
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