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Chemiluminescence | Liquid-Phase *
chapterposted on 2019-01-01, 00:00 authored by Zoe SmithZoe Smith, Jacqui AdcockJacqui Adcock, Neil BarnettNeil Barnett, Paul FrancisPaul Francis
The article provides a concise introduction to the liquid-phase chemiluminescence reagents that are responsible for the majority of analytical applications; namely acidic potassium permanganate, acridinium esters, diaryloxalates, dioxetanes, hypohalites, luminol, manganese(IV), and tris(2,2'-bipyridine)ruthenium(III) and related metal complexes. The substantial body of theoretical and practical work on the determination of reaction mechanisms and characterization of the key intermediates for these chemiluminescent processes is also described. This knowledge affords optimization and analyte selectivity to be achieved on a fundamental basis. The utility of these detection chemistries coupled to flow analysis, high-performance liquid chromatography (HPLC), capillary electrophoresis (CE), immunoassay, and DNA assays is briefly discussed.
Title of bookEncyclopedia of Analytical Science
SeriesReference Module in Chemistry, Molecular Sciences and Chemical Engineering
Pagination399 - 411
Place of publicationAmsterdam, Netherlands
Notes* Change History: September 2018. Zoe M Smith and Paul S Francis added the section on Other Metal Complexes. Zoe M Smith, Jacqui L Adcock, Paul S Francis and Neil W Barnett added references and updates throughout text. September 2013: Neil W Barnett added an abstract. Jacqui L Adcock and Paul S Francis added references and updates throughout text. This is an update of Zoe M. Smith, Jacqui L. Adcock, Neil W. Barnett, Paul S. Francis, Chemiluminescence—Liquid Phase, Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, Elsevier, 2014.
Publication classificationB Book chapter; D2 Reference work
Copyright notice2019, Elsevier
Editor/Contributor(s)Paul Worsfold, Alan Townshend, Colin Poole, Manuel Miró
Read the peer-reviewed publication
aminobutylethylisoluminolacridinium esterbis(2,4,6-trichlorophenyl)oxalatecapillary electrophoresischemiluminescencederivatizing agentdioxetaneflow analysisflow injection analysishigh-performance liquid chromatographyhypohaliteimmunoassayluminolManganese(IV)peroxyoxalatepotassium permanganatesulfiteTris(2,2′-bipyridine)ruthenium(III)