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An H-shaped, small molecular non-fullerene acceptor for efficient organic solar cells with an impressive open-circuit voltage of 1.17 V
journal contribution
posted on 2017-08-01, 00:00 authored by Akhil Gupta, Anushri Rananaware, Pedada Srinivasa Rao, Duong Duc La, Ante Bilic, Wanchun Xiang, Jingliang LiJingliang Li, Richard A Evans, Sidhanath V Bhosale, Sheshanath V BhosaleA bifluorenylidene-functionalized, H-shaped, small molecular non-fullerene electron acceptor, 6,6′,6′′,6′′′-([9,9′-bifluorenylidene]-2,2′,7,7′-tetrayltetrakis(thiophene-5,2-diyl))tetrakis(2,5-bis(2-ethylhexyl)-3-(thiophen-2-yl)-2,5-dihydrop yrrolo[3,4-c]pyrrole-1,4-dione) (coded as H1), which used diketopyrrolopyrrole as terminal functionalities, was designed, synthesized and characterized. H1 displayed a very high optical absorption coefficient, good solubility and thermal stability, promising optoelectronic properties, and high electron mobility, and afforded an encouraging efficiency of 5.42% when paired with the archetypal electron donor poly(3-hexylthiophene).
History
Journal
Materials chemistry frontiersVolume
1Issue
8Pagination
1600 - 1606Publisher
The Royal Society PublishingLocation
London, Eng.Publisher DOI
eISSN
2052-1537Language
engPublication classification
C1 Refereed article in a scholarly journalCopyright notice
2017, The Royal Society of Chemistry and the Chinese Chemical SocietyUsage metrics
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renewable energy technologiessolar energyadvantageslow costlight weightflexibilitybulk heterojunction (BHJ)Science & TechnologyPhysical SciencesTechnologyChemistry, MultidisciplinaryMaterials Science, MultidisciplinaryChemistryMaterials ScienceELECTRON-ACCEPTORDIKETOPYRROLOPYRROLEFUNCTIONALITIESCHROMOPHORES
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