zammit-chemiluminescencefromosmium-2012.pdf (204.08 kB)
Chemiluminescence from osmium(ii) complexes with phenanthroline, diphosphine and diarsine ligands
journal contribution
posted on 2012-01-01, 00:00 authored by Elizabeth Maree Zammit, Gregory Barbante, B Carlson, Egan DoevenEgan Doeven, Neil BarnettNeil Barnett, C Hogan, M Richter, Paul FrancisPaul FrancisThe reaction of various [Os(L)2(L′)]2+ complexes (where L and L′ are phenanthroline, diphosphine or diarsine ligands) and organic reducing agents after chemical or electrochemical oxidation of the reactants produces an emission of light corresponding to MLCT transitions. In certain instances, the emission was greater than that of [Ru(bipy)3]2+, but the relative signals were dependent on many factors, including reagent concentration, mode of oxidation, reducing agent and the sensitivity of the photodetector over the wavelength range.
History
Journal
AnalystVolume
137Issue
12Pagination
2766 - 2769Publisher
Royal Society of ChemistryLocation
Cambridge, EnglandPublisher DOI
ISSN
0003-2654eISSN
1364-5528Language
engPublication classification
C1 Refereed article in a scholarly journalCopyright notice
2012, The Royal Society of ChemistryUsage metrics
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