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Competition between cluster fragmentation, C–C bond coupling and C–X bond activation in silver hexynyl cluster cations, [(C4H9CCAg)nAg]+. Size does matter!
journal contribution
posted on 2009-01-01, 00:00 authored by F Q Wang, G N Khairallah, G A Koutsantonis, C M Williams, Damien CallahanDamien Callahan, R A J O’HairSilver hexynyl cluster cations, [(C4H9CCAg)nAg]+, exhibit a rich unimolecular chemistry that is dependant on the cluster size, n (1–5), cluster fragmentation (for all n > 1); C–C bond coupling (n = 3 & 4); C–H bond activation with comcomitant silver hydride formation (n = 1 & 4); C–C bond activation (n = 1 & 4).
History
Journal
Physical chemistry chemical physicsVolume
11Issue
21Season
Article Number : 4132Article number
4132Pagination
1 - 4Publisher
Royal Society of ChemistryLocation
London, Eng.Publisher DOI
ISSN
1463-9076eISSN
1463-9084Language
engPublication classification
C Journal article; C1.1 Refereed article in a scholarly journalCopyright notice
2009, Royal Society of ChemistryUsage metrics
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