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Conversion of carbon dioxide into cyclic carbonates using wool powder-KI as catalyst
journal contribution
posted on 2018-03-01, 00:00 authored by H Chang, Q Li, X Cui, Hong Wang, Z Bu, C Qiao, Tong LinChemical conversion of carbon dioxide (CO2) into usable materials offer opportunities to use carbon dioxide as a sustainable carbon source, but remains difficult to make. In this study, wool powder (WP), fine particles produced from natural wool fibers, was used as a catalyst for cycloaddition coupling of CO2with propylene oxide (PO) to form propylene carbonate (PC) in a solvent free condition. Potassium halide (KCl, KBr and KI), tetrabutylammonium iodide (TBAI), 1, 8-diazabicyclo[5.4.0]-undec-7-ene (DBU), and N, N-dimethylaminopyridine (DMAP) were used separately as co-catalyst. A synergetic effect was found between WP and KI, which shows the optimal efficiency when a low amount of the catalyst (e.g. 1.0 mol% KI relative to PO, WP: KI = 2:1 wt/wt) was employed at 1.5 MPa and 120 °C. The catalyst can be repeatedly used for five cycles without apparently losing the activity. It could be used to catalyze coupling of other mono-substituted terminal epoxides with CO2. Wool powder-KI may serve as an efficient, green catalyst system for the fixation of CO2.
History
Journal
Journal of CO2 utilizationVolume
24Pagination
174 - 179Publisher
ElsevierLocation
Amsterdam, The NetherlandsPublisher DOI
ISSN
2212-9820Language
engPublication classification
C1 Refereed article in a scholarly journalCopyright notice
2017, ElsevierUsage metrics
Keywords
Carbon dioxideWool powderEpoxideCycloaddition reactionSynergetic effectScience & TechnologyPhysical SciencesTechnologyChemistry, MultidisciplinaryEngineering, ChemicalChemistryEngineeringCHEMICAL FIXATIONIONIC LIQUIDSEFFICIENT SYNTHESISSYNERGISTIC CATALYSTSEPOXIDESCO2CYCLOADDITIONCHITOSANSOLVENTACIDInorganic Chemistry
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