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Crystal structure of a ceIII/feIII heterobimetallic complex

journal contribution
posted on 2003-08-01, 00:00 authored by G Deacon, C Forsyth, Maria ForsythMaria Forsyth
A central μ3—O moiety linking two FeIII and one CeIII sites supported by two distinct heterometallic carboxylate bridging modes features in self-assembled [CeFe2(bpy)2(μ3—O)(μ—L)2(μ—LH)2(LH)(H2O)2]·0.5(bpy)·7H2O (1) (LH2 = glycolic acid), and the structure models potential bonding modes of the Rare Earth corrosion inhibitor Ce(glycolate)3 to iron or iron oxide.

History

Journal

Zeitschrift für anorganische und allgemeine chemie

Volume

629

Issue

9

Pagination

1472 - 1474

Publisher

Wiley Interscience

Location

Malden, Ma.

Publisher DOI

ISSN

0044-2313

eISSN

1521-3749

Language

eng

Publication classification

C1.1 Refereed article in a scholarly journal

Copyright notice

2003, WILEY-VCH Verlag GmbH & Co. KGaA

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    Keywords

    ceriumglycolateironoxidecorrosionScience & TechnologyPhysical SciencesChemistry, Inorganic & NuclearChemistryInorganic Chemistry

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    All Rights Reserved

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