File(s) under permanent embargo
Defective carbon-doped boron nitride nanosheets for highly efficient electrocatalytic conversion of N2 to NH3
journal contribution
posted on 2020-04-06, 00:00 authored by Z Liu, M Zhang, H Wang, D Cang, X Ji, B Liu, Wenrong YangWenrong Yang, D Li, J LiuIn industry, ammonia (NH3) is currently produced by Haber-Bosch technology, which suffers from the drawbacks of high energy consumption and CO2 emission. Artificial N2 fixation in aqueous solution under ambient conditions has been recently pushed forward by developing electrocatalysts with high efficiency and high selectivity for NH3 production. Herein, we demonstrate that defective carbon-doped boron nitride nanosheets (C-BN) show excellent electrocatalytic activity and durability in N2 fixation. To be used as a cathode catalyst, C-BN achieves an NH3 production rate of 36.7 μg h-1 mgcat-1 at -0.55 V vs a reversible hydrogen electrode (RHE), which is much higher than that of the synthesized and exfoliated boron nitride nanosheets. The faradic efficiency of C-BN attains 6.51% at -0.55 V vs RHE, which indicates excellent selectivity of the N2 reduction reaction (NRR). Furthermore, the catalysts show great stability during electrolysis and recycling tests. In principle, carbon doping and the defective structure contribute to the promoted NRR performance of C-BN.
History
Journal
ACS sustainable chemistry and engineeringVolume
8Issue
13Pagination
5278 - 5286Publisher
American Chemical SocietyLocation
Washington, D.C.Publisher DOI
eISSN
2168-0485Language
engPublication classification
C Journal article; C1 Refereed article in a scholarly journalUsage metrics
Categories
No categories selectedKeywords
nitrogen fixationboron nitride nanosheetcarbon dopingelectrocatalysisstructural defectScience & TechnologyPhysical SciencesTechnologyChemistry, MultidisciplinaryGreen & Sustainable Science & TechnologyEngineering, ChemicalChemistryScience & Technology - Other TopicsEngineeringAMMONIA-SYNTHESISELECTROCHEMICAL SYNTHESISAMBIENT CONDITIONSHYDROGENNITROGENFIXATIONGRAPHENEWATERNANOSTRUCTURESCONDUCTIVITY
Licence
Exports
RefWorks
BibTeX
Ref. manager
Endnote
DataCite
NLM
DC