Depolymerization of aryltellurinic anhydrides with sodium hydroxide. Synthesis and structure of the hydrated sodium aryltellurinates [Na(H2O)4](RTeO2) (R = 4-MeOC6H4, 8-Me2NC10H6)
journal contribution
posted on 2012-01-01, 00:00authored byJ Beckmann, Andrew DuthieAndrew Duthie, T Gesing, T Koehne, E Lork
Depolymerization of the aryltellurinic anhydrides [(RTe)2O3]n (9, R = 4-MeOC6H4; 6, R = 8-Me2NC10H6) with aqueous NaOH afforded the hydrated sodium aryltellurinates [Na(H2O)4](4-MeOC6H4TeO2) (10) and [Na(H2O)4](8-Me2NC10H6TeO2)·H2O (11·H2O) as highly crystalline materials.