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Depolymerization of aryltellurinic anhydrides with sodium hydroxide. Synthesis and structure of the hydrated sodium aryltellurinates [Na(H2O)4](RTeO2) (R = 4-MeOC6H4, 8-Me2NC10H6)

journal contribution
posted on 2012-01-01, 00:00 authored by J Beckmann, Andrew DuthieAndrew Duthie, T Gesing, T Koehne, E Lork
Depolymerization of the aryltellurinic anhydrides [(RTe)2O3]n (9, R = 4-MeOC6H4; 6, R = 8-Me2NC10H6) with aqueous NaOH afforded the hydrated sodium aryltellurinates [Na(H2O)4](4-MeOC6H4TeO2) (10) and [Na(H2O)4](8-Me2NC10H6TeO2)·H2O (11·H2O) as highly crystalline materials.

History

Journal

Organometallics

Volume

31

Issue

8

Pagination

3451 - 3454

Publisher

American Chemical Society

Location

Washington, D. C.

ISSN

0276-7333

eISSN

1520-6041

Language

eng

Publication classification

C1 Refereed article in a scholarly journal

Copyright notice

2012, American Chemical Society