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Development of a predictive model for study of skin-core phenomenon in stabilization process of PAN precursor
journal contribution
posted on 2017-05-25, 00:00 authored by G Golkarnarenji, Minoo NaebeMinoo Naebe, J S Church, Khash Badii, A Bab-Hadiashar, S Atkiss, H KhayyamStudying the presence and progress of fiber defects, such as skin-core structure, is an important tool for analysis of a chemical process. In this article, the skin core morphology has been analyzed by optical microscopic (OM) images and Fourier transform infrared attenuated total reflectance mapping (FTIR-ATR mapping). The results of FTIR-ATR mapping showed that the fiber is almost uniform in the core area while OM images are accurate enough to be used for skin-core analysis. Using OM images, the core ratio of samples were measured to quantify the skin-core structure. Non-parametric kernel density estimation methods have then been compared with conventional parametric distribution models using these data. The results reveal that the parametric methods cannot adequately describe the skin-core phenomenon and that the non-parametric distributions are more appropriate for the quantification of skin-core morphology. By applying the non-parametric distributions, a model has been developed, which describes the relationship between the skin-core defect and the operation parameters of the fiber production. This approach can be used to predict the probability of skin-core occurrence and can be used to decrease the presence of this phenomenon in the carbon fibers production industry. Our results show that temperature is one of the most significant operational parameter at a typical oxygen concentration (in air at atmospheric pressure) governing the skin-core formation.
History
Journal
Journal of industrial and engineering chemistryVolume
49Pagination
46 - 60Publisher
ElsevierLocation
Amsterdam, The NetherlandsPublisher DOI
ISSN
1226-086XeISSN
1876-794XLanguage
engPublication classification
C1 Refereed article in a scholarly journalCopyright notice
2016, Korean Society of Industrial and Engineering ChemistryUsage metrics
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No categories selectedKeywords
thermal stabilizationskin-core morphologynon-parametric density estimationprobability density functionnon-linear predictive modellingstochastic modelScience & TechnologyPhysical SciencesTechnologyChemistry, MultidisciplinaryEngineering, ChemicalChemistryEngineeringTHERMAL-OXIDATIVE STABILIZATIONCARBON-FIBERSDENSITYMICROSTRUCTUREOPTIMIZATIONSURFACE
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