Direct electrospinning of nanofibre yarns using a rotating ring collector

Nanofibres prepared by electrospinning typically have randomly oriented fibrous structure. They have large surface-to-volume (or weight) ratio and excellent porous characteristic, which have shown enormous potential in diverse applications. However, electrospun nanofibres are often prepared in the form of randomly orientated fibrous web, which are fragile and difficult to be tailored in fibrous structures. Herein, we demonstrate a novel yarn electrospinning method which uses a rotating ring collector to convert newly electrospun nanofibres directly into a continuous yarn. The use of ring collector separates the yarn formation from the electrospinning zone. The deposition of later-spun nanofibres to the inner surface of fibrous cone eliminates hooked or curled nanofibres in the final yarn. The effects of polymer concentration and operating parameters on nanofibre and yarn morphology, diameter and the ring collector on yarn twist feature were examined. The nanofibre yarns had a surface twist angle up to 54.4°, and tensile strength as high as 93.6 MPa (elongation at break 242.6%). Increasing twist levels improves tensile strength and strain values.