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Electrochemical and optical properties of a redox-active Cu(ii) coordination framework incorporating the tris(4-(pyridin-4-yl)phenyl)amine ligand

journal contribution
posted on 2022-10-24, 05:18 authored by Carol Hua, P Turner, D M D'Alessandro
A new redox-active ligand, tris(4-(pyridin-4-yl)phenyl)amine (Npy 3), has been synthesised, and incorporated into the coordination framework [Cu(Npy3)Cl2]·DMF. The monoradical cation of the ligand is readily accessible, thus enabling chemical oxidation of the framework. The novel Npy3 ligand has significant potential as a structural motif for the development of multifunctional frameworks. © 2013 The Royal Society of Chemistry.

History

Journal

Dalton Transactions

Volume

42

Pagination

6310 - 6313

ISSN

1477-9226

eISSN

1477-9234