Version 2 2024-06-16, 13:43Version 2 2024-06-16, 13:43
Version 1 2014-10-27, 16:26Version 1 2014-10-27, 16:26
journal contribution
posted on 2024-06-16, 13:43authored byD Dakternieks, Andrew DuthieAndrew Duthie, K Jurkschat, M Schurmann, E Tiekink
Preliminary results are described on the synthesis and characterization of novel spacer-bridged tetraorganodistannoxanes, {[[R(Cl)Sn]2(CH2)2]O}4 (n = 5 – 8, 10, 12; R = CH2SiMe3) containing particularly long organic spacers. In the solid state, these compounds reveal typical double-ladder structures with eight tin atoms per molecule, whereas in solution a partial and reversible rearrangement takes place to form tetraorganodistannoxanes, {[[R(Cl)Sn]2(CH2)n]O}2 (n = 5 – 8, 10, 12; R = CH2SiMe3), having four tin atoms per molecule.
History
Journal
Main group metal chemistry
Volume
25
Pagination
73-76
Location
London, England
Open access
Yes
ISSN
0334-7575
eISSN
0792-1241
Language
eng
Publication classification
C1 Refereed article in a scholarly journal, C Journal article