File(s) under permanent embargo
Facile synthesis of Au/Pd nano-dogbones and their plasmon-enhanced visible-to-NIR light photocatalytic performance
journal contribution
posted on 2022-10-26, 04:32 authored by Y Yin, Y Yang, L Zhang, Y Li, Z Li, Weiwei LeiWeiwei Lei, Y Ma, Z HuangHere, we report a facile synthesis of Pd/Au nano-dogbones (NDBs) by loading massive Pd nanoparticles on the two ends of Au nanorods (NRs) via a seed-mediated method. The as-prepared samples were investigated by using TEM, elemental analysis, UV-vis and FDTD simulation. The photocatalytic activity of Pd/Au NDBs was assessed by dehydrogenation of formic acid under visible-to-NIR light irradiation. The Pd/Au NDBs shows much higher enhanced reaction activity compared with samples with core-shell structure due to the increased electron and hole pair separation and total catalytic sites. More importantly, the introduction of Au NRs broadens the photoresponse range and improves the utilization of sunlight efficiently. This finding provides a rational approach to improve photocatalytic performance by forming dogbone structures via integrating plasmonic metals and conventional catalysts.
History
Journal
RSC AdvancesVolume
7Pagination
36923 - 36928Publisher DOI
eISSN
2046-2069Copyright notice
2017, The Royal Society of ChemistryUsage metrics
Categories
No categories selectedKeywords
Science & TechnologyPhysical SciencesChemistry, MultidisciplinaryChemistryFORMIC-ACID DEHYDROGENATIONHYDROGEN GENERATIONAU NANORODSEFFICIENT CONVERSIONAMBIENT CONDITIONSENERGY-CONVERSIONROOM-TEMPERATURECHEMICAL ENERGYSINGLE-PARTICLEGOLD NANORODSPd\/Au nano-dogbones (NDBs)Pd nanoparticlesAu nanorods (NRs)Pd\/Au NDBsTEMelemental analysisUV-visFDTD simulationphotocatalytic activity
Licence
Exports
RefWorks
BibTeX
Ref. manager
Endnote
DataCite
NLM
DC