Fluorescence application to hydrocarbon monitoring in North West Shelf marine waters

The application of fluorometry to hydrocarbon detection in marine waters is a standard procedure in many parts of the world. This technology is advantageous because spatial and temporal variations in hydrocarbon distributions can be acquired readily and rapidly in a cost-effective manner compared to traditional sampling methods. Its application to North West Shelf marine waters has been examined through two recent research studies. In the first study, the fluorescent properties of North West Shelf hydrocarbons were compared to those from North America. In general, peak fluorescence of North West Shelf samples are lower than North American and European hydrocarbons. Hence, fluorometer specifications (e.g. excitation and emission wavelengths) need to be tailored for hydrocarbon detection within North West Shelf waters. The second study measured low background fluorescence of a representative region of the North West Shelf using the fluorometer specifications recommended in the first study. This indicates that background fluorescence is unlikely to affect hydrocarbon detection in the marine waters of the North West Shelf. These studies support the use of fluorometry as a technique to reliably detect and to monitor unplanned (e.g. spills) and planned (e.g. producted formation water) hydrocarbon discharges across the North West Shelf.