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Green chemical tools in organophosphorus chemistry-organophosphorus tools in green chemistry
journal contribution
posted on 2011-05-13, 00:00 authored by G Kglevich, A Grün, E Bálint, N Z Kiss, R Kovács, I G Molnár, Z Blastik, R V Tóth, A Fehérvári, I CsontosA variety of reactions including esterifications, alkylations, additions, cycloadditions, fragmentations, and condensations were carried out under microwave MW-assisted and solventless conditions, occasionally in ionic liquids (ILs). In a few cases, MW was synergic with phase transfer catalysis or could substitute it. A variety of P(III) ligands were developed and converted to Pt(II) complexes that can be used as catalysts. Finally, phosphorylations and the Kabachnik-Fields reaction were monitored and optimized by an on-line method, in situ Fourier transform IR spectroscopy.
History
Journal
Phosphorus, sulfur and silicon and the related elementsVolume
186Issue
4Season
Special Issue : 18th International Conference on Phosphorus Chemistry 9ICPC2010)Pagination
613 - 620Publisher
Taylor & Francis GroupLocation
New York, N.Y.Publisher DOI
ISSN
1042-6507eISSN
1563-5325Language
engPublication classification
C1.1 Refereed article in a scholarly journalCopyright notice
2011, Taylor & Francis GroupUsage metrics
Keywords
green chemistryin situ Fourier transform IR spectroscopyMW-assisted organic synthesisorganophosphorus chemistryphase transfer catalysisPt(II)-P(III) complexesScience & TechnologyPhysical SciencesChemistry, Inorganic & NuclearChemistry, OrganicChemistryALPHA-AMINO PHOSPHONATESPHASE-TRANSFER CATALYSISTRANSFORM INFRARED-SPECTROSCOPY6-MEMBERED P-HETEROCYCLESSOLID-LIQUID PHASEONE-POT SYNTHESISMICROWAVE-ASSISTED SYNTHESISSOLVENT-FREE CONDITIONSEFFICIENT SYNTHESISDIETHYL CHLOROPHOSPHATEOrganic ChemistryInorganic Chemistry