Deakin University
Browse

File(s) under permanent embargo

Highly rigid and stable porous Cu(i) metal-organic framework with reversible single-crystal-to-single-crystal structural transformation

Version 2 2024-06-17, 20:09
Version 1 2016-12-05, 15:18
journal contribution
posted on 2024-06-17, 20:09 authored by S Mohapatra, H Sato, R Matsuda, S Kitagawa, TK Maji
A simple room temperature reaction of Cu(NO3)2, and 2,3-pyrazinedicarboxylic acid (H2pyzdc) in the presence of dihydroxyfumaric acid (DHFA) resulted in the formation of a highly stable 3D Cu(I) coordination polymer, {[Cu2(pyzdc)]·0.83H2O}n where DHFA acts as a reducing agent. It possesses a 1D water filled channel along the crystallographic c direction and the framework shows reversible single-crystal-to-single-crystal structural transformation upon dehydration and rehydration.

History

Journal

Crystengcomm

Volume

14

Pagination

4153-4156

Location

London, Eng.

eISSN

1466-8033

Language

eng

Publication classification

C Journal article, C1.1 Refereed article in a scholarly journal

Copyright notice

2012, The Royal Society of Chemistry

Issue

12

Publisher

Royal Society of Chemistry