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In-Situ-Activated N-Doped Mesoporous Carbon from a Protic Salt and Its Performance in Supercapacitors
journal contribution
posted on 2016-12-28, 00:00 authored by T C Mendes, C Xiao, F Zhou, H Li, G P Knowles, Matthias Hilder, Anthony SomersAnthony Somers, Patrick HowlettPatrick Howlett, D R MacFarlaneProtic salts have been recently recognized to be an excellent carbon source to obtain highly ordered N-doped carbon without the need of tedious and time-consuming preparation steps that are usually involved in traditional polymer-based precursors. Herein, we report a direct co-pyrolysis of an easily synthesized protic salt (benzimidazolium triflate) with calcium and sodium citrate at 850 °C to obtain N-doped mesoporous carbons from a single calcination procedure. It was found that sodium citrate plays a role in the final carbon porosity and acts as an in situ activator. This results in a large surface area as high as 1738 m2/g with a homogeneous pore size distribution and a moderate nitrogen doping level of 3.1%. X-ray photoelectron spectroscopy (XPS) measurements revealed that graphitic and pyridinic groups are the main nitrogen species present in the material, and their content depends on the amount of sodium citrate used during pyrolysis. Transmission electron microscopy (TEM) investigation showed that sodium citrate assists the formation of graphitic domains and many carbon nanosheets were observed. When applied as supercapacitor electrodes, a specific capacitance of 111 F/g in organic electrolyte was obtained and an excellent capacitance retention of 85.9% was observed at a current density of 10 A/g. At an operating voltage of 3.0 V, the device provided a maximum energy density of 35 W h/kg and a maximum power density of 12 kW/kg.
History
Journal
ACS Applied Materials and InterfacesVolume
8Issue
51Pagination
35243 - 35252Publisher DOI
ISSN
1944-8244eISSN
1944-8252Publication classification
C1 Refereed article in a scholarly journalCopyright notice
2016, American Chemical SocietyUsage metrics
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No categories selectedKeywords
Science & TechnologyTechnologyNanoscience & NanotechnologyMaterials Science, MultidisciplinaryScience & Technology - Other TopicsMaterials ScienceN-doped carbonmesoporous carbonprotic saltssymmetric supercapacitorsone-step calcinationcitrate saltsDOUBLE-LAYER CAPACITORSPOROUS CARBONOXYGEN REDUCTIONENERGY-STORAGEELECTROCHEMICAL CAPACITORSELECTRODE MATERIALSTEMPLATE SYNTHESISIONIC LIQUIDSPRECURSORADSORPTION
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