Intramolecular photochemical [2 + 1]-cycloadditions of nucleophilic siloxy carbenes†

Bunyamin, A; Hua, C; Polyzos, A; Priebbenow, DL

Intramolecular photochemical [2 + 1]-cycloadditions of nucleophilic siloxy carbenes†

journal contribution

posted on 2024-06-19, 09:36 authored by A Bunyamin, C Hua, A Polyzos, DL Priebbenow

Visible light induced singlet nucleophilic carbenes undergo rapid [2 + 1]-cycloaddition with tethered olefins to afford unique bicyclo[3.1.0]hexane and bicyclo[4.1.0]heptane scaffolds.

History

Journal

Chemical Science

Volume

13

Pagination

3273-3280

Location

Cambridge, Eng.

Publisher DOI

https://doi.org/10.1039/d2sc00203e

Open access

Yes

Link to full text

http://doi.org/10.1039/d2sc00203e

ISSN

2041-6520

eISSN

2041-6539

Language

English

Author URL

http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000762978700001&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=a045e4b2bb1f2b747c68c720ec8913b7

Publication classification

C1 Refereed article in a scholarly journal

Issue

11

Publisher

Royal Society of Chemistry

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Keywords

ACYLSILANES ALKENES CATALYZED ENANTIOSELECTIVE CYCLOPROPANATION C-C Chemistry Chemistry, Multidisciplinary DONOR-ACCEPTOR CYCLOPROPANES FUNCTIONALIZATION METAL-FREE Physical Sciences Science & Technology SILYLACYLATIONS STEREOSELECTIVITY TRANSFORMATIONS 3404 Medicinal and biomolecular chemistry 3405 Organic chemistry

Licence

CC BY-NC 4.0

Intramolecular photochemical [2 + 1]-cycloadditions of nucleophilic siloxy carbenes†

History

Journal

Volume

Pagination

Location

Publisher DOI

Open access

Link to full text

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eISSN

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Author URL

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Publisher

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