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Ionic liquids and plastic crystals with a symmetrical pyrrolidinium cation
journal contribution
posted on 2018-01-01, 00:00 authored by Ruhamah Yunis, T W Newbegin, A F Hollenkamp, Jenny PringleJenny PringleSolid and liquid salts utilising the N-methyl-N-alkyl pyrrolidinium cation, [Cnmpyr]+, and their use in electrochemical devices, are well established. However, new materials with enhanced properties, such as higher conductivity, lower viscosity or more favourable thermal phase behaviour, are still required. Here we report the synthesis and characterisation of new ionic liquids and plastic crystals using the N,N-diethylpyrrolidinium cation ([C2epyr]+) with six different anions. With the fluorosulfonyl(trifluoromethanesulfonyl)imide ([FTFSI]) and dicyanamide ([DCA]) anions, room temperature ionic liquids with low viscosity are formed. With the bis(trifluoromethanesulfonyl)imide ([NTf2]), bis(fluorosulfonyl)imide ([FSI]), hexafluorophosphate ([PF6]) and tetrafluoroborate ([BF4]) anions, organic ionic plastic crystals are produced. Of the new solid salts, [C2epyr][FSI] has the highest conductivity, higher than the well-established methyl-substituted analogue, giving 1.9 105 S cm1 at 30 1C. Thermal analysis, conductivity and the Walden relationship are used to compare the new N,N-diethylpyrrolidinium salts across the different anions and with some previously reported N-methyl-N-alkylpyrrolidinium salts.
History
Journal
Materials chemistry frontiersVolume
2Issue
6Pagination
1207 - 1214Publisher
Royal Society of ChemistryLocation
Cambridge, Eng.Publisher DOI
eISSN
2052-1537Language
engPublication classification
C1 Refereed article in a scholarly journalCopyright notice
2018, The Royal Society of Chemistry and the Chinese Chemical SocietyUsage metrics
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