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Organometallic macrocyclic chemistry. 8. (1) an unusual metallacycle derived from phosphine-alkynyl thioether coupling

Version 2 2024-06-05, 00:22
Version 1 2018-09-10, 10:55
journal contribution
posted on 2024-06-05, 00:22 authored by AF Hill, B Niess, Madeleine SchultzMadeleine Schultz, AJP White, DJ Williams
The α,ω-diyne 4,7,10-trithiatrideca-2,11-diyne reacts with [RuCl2(PPh3)3] and KPF6to form the phosphonio-substituted metallatricyclic salt [RuCl(PPh3) {κ4C,S,S′,S″-S(C≡CMe)C2H4SC2H4SC(PPh3)CMe}]PF6arising from the activation of one alkynyl group toward nucleophilic attack by extraneous phosphine. © 2010 American Chemical Society.

History

Journal

Organometallics

Volume

29

Pagination

6488-6492

Location

Washington, D.C.

ISSN

0276-7333

eISSN

1520-6041

Language

eng

Publication classification

C Journal article, C1.1 Refereed article in a scholarly journal

Copyright notice

2010, American Chemical Society

Issue

23

Publisher

ACS Publishing