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Oxygen transfer from an intramolecularly coordinated diaryltellurium oxide to acetonitrile. Formation and combined AIM and ELI-D analysis of a novel diaryltellurium acetimidate.
Version 2 2024-06-06, 08:58
Version 1 2015-04-25, 12:41
journal contribution
posted on 2024-06-06, 08:58 authored by O Mallow, J Bolsinger, P Finke, M Hesse, YS Chen, Andrew DuthieAndrew Duthie, S Grabowsky, P Luger, S Mebs, J BeckmannThe reaction of the intramolecularly coordinated diaryltellurium(IV) oxide (8-Me2NC10H6)2TeO with acetonitrile proceeds with oxygen transfer and gives rise to the formation of the novel zwitterionic diaryltelluronium(IV) acetimidate (8-Me2NC10H6)2TeNC(O)CH3 (1) in 57% yield. Hydrolysis of 1 with hydrochloric acid affords acetamide and the previously known diarylhydroxytelluronium(IV) chloride [(8-Me2NC10H6)2Te(OH)]Cl.
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Journal
Journal of the American Chemical SocietyVolume
136Pagination
10870-10873Location
Washington, DCPublisher DOI
eISSN
1520-5126Language
engPublication classification
C Journal article, C1 Refereed article in a scholarly journalCopyright notice
2014, American Chemical SocietyIssue
31Publisher
American Chemical SocietyUsage metrics
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