Deakin University
Browse

File(s) not publicly available

Oxygen transfer from an intramolecularly coordinated diaryltellurium oxide to acetonitrile. Formation and combined AIM and ELI-D analysis of a novel diaryltellurium acetimidate.

journal contribution
posted on 2014-08-06, 00:00 authored by O Mallow, J Bolsinger, P Finke, M Hesse, Y S Chen, Andrew DuthieAndrew Duthie, S Grabowsky, P Luger, S Mebs, J Beckmann
The reaction of the intramolecularly coordinated diaryltellurium(IV) oxide (8-Me2NC10H6)2TeO with acetonitrile proceeds with oxygen transfer and gives rise to the formation of the novel zwitterionic diaryltelluronium(IV) acetimidate (8-Me2NC10H6)2TeNC(O)CH3 (1) in 57% yield. Hydrolysis of 1 with hydrochloric acid affords acetamide and the previously known diarylhydroxytelluronium(IV) chloride [(8-Me2NC10H6)2Te(OH)]Cl.

History

Journal

Journal of the American Chemical Society

Volume

136

Issue

31

Pagination

10870 - 10873

Publisher

American Chemical Society

Location

Washington, DC

eISSN

1520-5126

Language

eng

Publication classification

C Journal article; C1 Refereed article in a scholarly journal

Copyright notice

2014, American Chemical Society