Deakin University
Browse
- No file added yet -

Photoexcited Pd(ii) auxiliaries enable light-induced control in C(sp³)-H bond functionalisation

Download (1.17 MB)
Version 3 2024-06-19, 06:02
Version 2 2024-06-04, 05:41
Version 1 2021-10-20, 08:29
journal contribution
posted on 2024-06-19, 06:02 authored by ML Czyz, GK Weragoda, TH Horngren, Tim ConnellTim Connell, D Gomez, RAJ O'Hair, A Polyzos

Visible light irradiation of 8-aminoquinoline Pd(ii) complexes initiates photoinduced electron transfer with alkyl halides, affording C–H halogenation over C–C bond adducts. A method for inert C(sp3)–H bond halogenation (Br, Cl and I) is reported.

History

Journal

Chemical Science

Volume

11

Pagination

2455-2463

Location

Cambridge, Eng.

Publisher DOI

Open access

  • Yes

Link to full text

ISSN

2041-6520

eISSN

2041-6539

Language

eng

Publication classification

C1.1 Refereed article in a scholarly journal

Issue

9

Publisher

Royal Society of Chemistry

Usage metrics

    Research Publications

    Categories

    No categories selected

    Keywords

    Science & TechnologyPhysical SciencesChemistry, MultidisciplinaryChemistryC-H ARYLATIONPALLADIUM-CATALYZED ALKYLATIONIONIZATION MASS-SPECTROMETRYALPHA-AMINO-ACIDSX-RAY-STRUCTUREREDUCTIVE ELIMINATIONOXIDATIVE ADDITIONHECK REACTIONPD(II)-CATALYZED BROMINATIONHIGHLY EFFICIENT3402 Inorganic chemistry

    Licence

    CC BY 4.0

    Exports

    RefWorks
    BibTeX
    Ref. manager
    Endnote
    DataCite
    NLM
    DC