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Polydatin-fatty acid conjugates are effective antioxidants for stabilizing omega 3-containing bulk fish oil and fish oil emulsions
journal contribution
posted on 2019-12-15, 00:00 authored by Taiwo Akanbi, S N Marshall, Colin BarrowColin BarrowCandida antarctica lipase B-catalysed synthesis of lipophilic esters of polydatin was investigated along with their antioxidant activities. The effects of synthesis parameters such as solvent, substrate molar ratio, enzyme concentration, addition of molecular sieves, reaction temperature and time on the production of ester were studied and optimised. The highest production of esters was obtained with acetone as the reaction solvent. The antioxidant activities of the esters were compared with those of commercial butylated hydroxytoluene (BHT) and α-tocopherol. All polydatin esters inhibited the oxidative destruction of β-carotene more effectively than did BHT and α-tocopherol. Results of thiobarbituric acid tests showed that in bulk fish oil, all esters were more effective than α-tocopherol at 2 mmol/kg concentration but were not as effective as BHT. In fish oil-emulsions, all esters were more effective than both BHT and α-tocopherol at 2 mmol/kg concentration. The synthesized polydatin esters are promising antioxidants for oil/fat-based foods.
History
Journal
Food chemistryVolume
301Article number
125297Pagination
1 - 8Publisher
ElsevierLocation
Amsterdam, The NetherlandsPublisher DOI
ISSN
0308-8146eISSN
1873-7072Language
engPublication classification
C Journal article; C1 Refereed article in a scholarly journalCopyright notice
2019, Elsevier LtdUsage metrics
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No categories selectedKeywords
PolydatinConjugatesLipaseAntioxidantOmega-3EmulsionStabilizeScience & TechnologyPhysical SciencesLife Sciences & BiomedicineChemistry, AppliedFood Science & TechnologyNutrition & DieteticsChemistryCANDIDA-ANTARCTICAENZYMATIC-SYNTHESISLIPID-PEROXIDATIONLIPOPHILIC RUTINRESVERATROLDERIVATIVESOXIDATIONPICEIDPOLYPHENOLS
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