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Programmable graphene doping via electron beam irradiation

journal contribution
posted on 29.06.2017, 00:00 authored by Y Zhou, J Jadwiszczak, D Keane, Ying (Ian) ChenYing (Ian) Chen, D Yu, H Zhang
Graphene is a promising candidate to succeed silicon based devices, and the conventional strategies for fabrication and testing of graphene-based electronics often utilise an electron beam. Here, we report on a systematic study of the effect of electron beam exposure on graphene devices. We realise reversible doping of on-chip graphene using a focused electron beam. Our results demonstrate site-specific control of carrier type and concentration achievable by modulating the charge distribution in the substrate. The effect of substrate-embedded charges on carrier mobility and conductivity of graphene is studied, with a dielectric screening model proposed to explain the effective n-type and p-type doping produced at different beam energies. Multiple logic operations are thus implemented in a single graphene sheet by using site-specific e-beam irradiation. We extend the phenomenon to MoS2, generalising it to conductive two-dimensional materials. Our results are of importance to imaging, in situ characterisation and lithographic techniques employed to investigate 2D materials.

History

Journal

Nanoscale

Volume

9

Issue

25

Pagination

8657 - 8664

Publisher

Royal Society of Chemistry

Location

Cambridge, Eng.

eISSN

2040-3372

Language

eng

Publication classification

C1 Refereed article in a scholarly journal

Copyright notice

2017, Royal Society of Chemistry