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Protonated melonate Ca[HC6N7(NCN)3]·7H2O – synthesis, crystal structure, and thermal properties

journal contribution
posted on 2009-12-01, 00:00 authored by S Makowski, Daniel Gunzelmann, J Senker, W Schnick
Calcium hydrogenmelonate heptahydrate Ca[HC6N7(NCN)3]·7H2O was obtained by metathesis reaction in aqueous solution. The structure of the molecular salt was elucidated by single-crystal X-ray diffraction. The crystal structure consists of alternating layers of planar monopronated melonate ions, Ca2+ and crystal water molecules. The anions of adjacent layers are staggered so that no π–π stacking occurs. The melonate entities are interconnected by hydrogen bonds within and between the layers. Ca[HC6N7(NCN)3]·7H2O was investigated by solid-state NMR and FTIR spectroscopy, TG and DTA measurements.

History

Journal

Journal of inorganic and general chemistry

Volume

635

Issue

15

Pagination

2434 - 2439

Publisher

Wiley

Location

London, Eng.

ISSN

1521-3749

Language

eng

Publication classification

C1.1 Refereed article in a scholarly journal

Copyright notice

2009, Wiley

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