redox-statedependent-2017.pdf (999.94 kB)
Redox-state dependent spectroscopic properties of porous organic polymers containing furan, thiophene, and selenophene
journal contribution
posted on 2017-01-01, 00:00 authored by Carol Hua, S Woo, A Rawal, F Tuna, J M Hook, D Collison, D M D'AlessandroA series of electroactive triarylamine porous organic polymers (POPs) with furan, thiophene, and selenophene (POP-O, POP-S, and POP-Se) linkers have been synthesised and their electronic and spectroscopic properties investigated as a function of redox state. Solid state NMR provided insight into the structural features of the POPs, while in situ solid state Vis-NIR and electron paramagnetic resonance spectroelectrochemistry showed that the distinct redox states in POP-S could be reversibly accessed. The development of redox-active porous organic polymers with heterocyclic linkers affords their potential application as stimuli responsive materials in gas storage, catalysis, and as electrochromic materials.
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Journal
Australian Journal of ChemistryVolume
70Issue
11Pagination
1227 - 1234Publisher
CSIRO PublishingLocation
Canberra, A.C.T.Publisher DOI
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ISSN
0004-9425eISSN
1445-0038Language
EnglishPublication classification
C1.1 Refereed article in a scholarly journalUsage metrics
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