Rhodium-induced fragmentation and rearrangement of 4,7,10-trithiatrideca-2,11-diyne

Caldwell, LM; Edwards, AJ; Hill, AF; Neumann, H; Schultz, Madeleine

Rhodium-induced fragmentation and rearrangement of 4,7,10-trithiatrideca-2,11-diyne

journal contribution

posted on 2024-06-05, 00:22 authored by LM Caldwell, AJ Edwards, AF Hill, H Neumann, Madeleine SchultzMadeleine Schultz

The reaction of 4,7,10-trithiatrideca-2,11-diyne with RhCl(PPh3)3results in cleavage and rearrangement of the diyne with formation of the structurally characterized complex RhCl(C≡CMe)(PPh3){κ3-S,S′,S″-S(CH= CH2)CH2CH2SCH=CMeS}.

History

Journal

Organometallics

Volume

22

Pagination

2531-2534

Publisher DOI

https://doi.org/10.1021/om030040m

ISSN

0276-7333

Language

eng

Publication classification

C Journal article, C1.1 Refereed article in a scholarly journal

Issue

12

Publisher

ACS Publications

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Keywords

School of Life and Environmental Sciences

Rhodium-induced fragmentation and rearrangement of 4,7,10-trithiatrideca-2,11-diyne

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