Rhodium-induced fragmentation and rearrangement of 4,7,10-trithiatrideca-2,11-diyne

Caldwell, L M; Edwards, A J; Hill, A F; Neumann, H; Schultz, Madeleine

File(s) under permanent embargo

Rhodium-induced fragmentation and rearrangement of 4,7,10-trithiatrideca-2,11-diyne

journal contribution

posted on 2003-06-09, 00:00 authored by L M Caldwell, A J Edwards, A F Hill, H Neumann, Madeleine SchultzMadeleine Schultz

The reaction of 4,7,10-trithiatrideca-2,11-diyne with RhCl(PPh3)3results in cleavage and rearrangement of the diyne with formation of the structurally characterized complex RhCl(C≡CMe)(PPh3){κ3-S,S′,S″-S(CH= CH2)CH2CH2SCH=CMeS}.

History

Journal

Organometallics

Volume

22

Issue

12

Pagination

2531 - 2534

Publisher

ACS Publications

Publisher DOI

https://doi.org/10.1021/om030040m

ISSN

0276-7333

Language

eng

Publication classification

C Journal article; C1.1 Refereed article in a scholarly journal

Usage metrics

Read the peer-reviewed publication

Rhodium-induced fragmentation and rearrangement of 4,7,10-trithiatrideca-2,11-diyne

Research Publications

Keywords

Science & Technology Physical Sciences Chemistry, Inorganic & Nuclear Chemistry, Organic Chemistry CRYSTAL-STRUCTURE ORGANIC-SYNTHESIS COMPLEXES ACTIVATION REACTIVITY THIOETHER MOLECULES ALKYNES RH IR

File(s) under permanent embargo

Rhodium-induced fragmentation and rearrangement of 4,7,10-trithiatrideca-2,11-diyne

History

Journal

Volume

Issue

Pagination

Publisher

Publisher DOI

ISSN

Language

Publication classification

Usage metrics

Read the peer-reviewed publication

Categories

Keywords

Licence

Exports