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Single step preparation of meso-porous and reduced graphene oxide by gamma-ray irradiation in gaseous phase
journal contribution
posted on 2014-04-01, 00:00 authored by Ludovic DumeeLudovic Dumee, Chunfang Feng, Li He, Zhifeng YiZhifeng Yi, Fenghua SheFenghua She, Zheng Peng, Weimin Gao, C Banos, J B Davies, C Huynh, S Hawkins, M C Duke, S Gray, Peter HodgsonPeter Hodgson, Lingxue KongLingxue KongA facile and highly efficient route to produce simultaneously porous and reduced graphene oxide by gamma ray irradiation in hydrogen is here demonstrated. Narrowly distributed nano-scale pores (average size of ∼3 nm and surface density >44,900 pore μm-2) were generated across 10 μm thick graphene oxide bucky-papers at a total irradiation dose of 500 kGy. The graphene oxide sheet reduction was confirmed to occur homogeneously across the structures by Fourier transform infrared spectroscopy and Raman analysis. This one-step, catalyst-free, high penetration and through-put technique, offers great promises potential for the mass production of reduced graphene oxide from cheap graphene oxide. © 2013 Elsevier Ltd. All rights reserved.