File(s) under permanent embargo
Small molecular non-fullerene acceptors based on naphthalenediimide and benzoisoquinoline-dione functionalities for efficient bulk-heterojunction devices
journal contribution
posted on 2017-08-01, 00:00 authored by D Srivani, Akhil Gupta, D D La, R S Bhosale, A L Puyad, W Xiang, Jingliang LiJingliang Li, S V BhosaleThrough the conjunction of naphthalenediimide and benzoisoquinoline-dione functionalities, two novel, solution-processable non-fullerene electron acceptors, 2,7-dioctyl-4,9-bis(2-octyl-1,3-dioxo-2,3-dihydro-1H-benzo[de]isoquinolin-6-yl)benzo[lmn] [3,8]phenanthroline-1,3,6,8(2H,7H)-tetraone (coded as NDI-N1) and 2,7-dioctyl-4,9-bis(5-(2-octyl-1,3-dioxo-2,3-dihydro-1H-benzo[de] isoquinolin-6-yl)thiophen-2-yl)benzo[lmn][3,8] phenanthroline-1,3,6,8(2H,7H)-tetraone (coded as NDI-N2), were designed, synthesized, and used as active components for bulk-heterojunction photovoltaic devices. The new chromophores were based on the acceptor–acceptor–acceptor module where naphthalenediimide unit served as the central acceptor flanked by terminal benzoisoquinoline-dione acceptor functionality. The optoelectronic and photovoltaic properties of NDI-N1 and NDI-N2 were directly compared. Solution-processable bulk-heterojunction devices were fabricated using NDI-N1 and NDI-N2 as non-fullerene electron acceptor materials. Studies on the photovoltaic properties revealed that the best poly(3-hexylthiophene) (P3HT): NDI-N2-based device showed an impressive enhanced power conversion efficiency of 4.04%, around 40% increase with respect to the efficiency of the best NDI-N1-based device (2.91%). It is justifiable to mention that the device outcome reported herein provides strong support and incentive for the current research strategy, and that the conjoint use of potential acceptor building blocks, such as naphthalenediimide and benzoisoquinoline-dione, can indeed generate efficient non-fullerene acceptors.
History
Journal
Dyes and pigmentsVolume
143Pagination
1 - 9Publisher
ElsevierLocation
Amsterdam, The NetherlandsPublisher DOI
ISSN
0143-7208eISSN
1873-3743Language
engPublication classification
C1 Refereed article in a scholarly journalCopyright notice
2017, ElsevierUsage metrics
Categories
No categories selectedKeywords
Solution-processableNaphthalenediimideBenzoisoquinoline-dioneBulk-heterojunctionAcceptoreacceptoreacceptorThiopheneScience & TechnologyPhysical SciencesTechnologyChemistry, AppliedEngineering, ChemicalMaterials Science, TextilesChemistryEngineeringMaterials ScienceAcceptor-acceptor-acceptorPOLYMER SOLAR-CELLSOPEN-CIRCUIT VOLTAGEELECTRON-ACCEPTORPHOTOVOLTAIC CELLS1.18 VDIKETOPYRROLOPYRROLEPERFORMANCECHROMOPHORESDERIVATIVESMORPHOLOGY
Licence
Exports
RefWorks
BibTeX
Ref. manager
Endnote
DataCite
NLM
DC