File(s) under permanent embargo
Strain-responsive polyurethane/PEDOT:PSS elastomeric composite fibers with high electrical conductivity
journal contribution
posted on 2014-05-28, 00:00 authored by Shayan Seyedin, Joselito RazalJoselito Razal, P C Innis, G G WallaceIt is a challenge to retain the high stretchability of an elastomer when used in polymer composites. Likewise, the high conductivity of organic conductors is typically compromised when used as filler in composite systems. Here, it is possible to achieve elastomeric fiber composites with high electrical conductivity at relatively low loading of the conductor and, more importantly, to attain mechanical properties that are useful in strain-sensing applications. The preparation of homogenous composite formulations from polyurethane (PU) and poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) that are also processable by fiber wet-spinning techniques are systematically evaluated. With increasing PEDOT:PSS loading in the fiber composites, the Young's modulus increases exponentially and the yield stress increases linearly. A model describing the effects of the reversible and irreversible deformations as a result of the re-arrangement of PEDOT:PSS filler networks within PU and how this relates to the electromechanical properties of the fibers during the tensile and cyclic stretching is presented. Conducting elastomeric fibers based on a composite of polyurethane (PU) and PEDOT:PSS, produced by a wet-spinning method, have high electrical conductivity and stretchability. These fibers can sense large strains by changes in resistance. The PU/PEDOT:PSS fiber is optimized to achieve the best strain sensing. PU/PEDOT:PSS fibers can be produced on a large scale and integrated into conventional textiles by weaving or knitting. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
History
Journal
Advanced Functional MaterialsVolume
24Issue
20Pagination
2957 - 2966Publisher
WileyLocation
London, Eng.Publisher DOI
ISSN
1616-301XeISSN
1616-3028Language
engPublication classification
C Journal article; C1.1 Refereed article in a scholarly journalCopyright notice
2014, Wiley-BlackwellUsage metrics
Categories
No categories selectedKeywords
conducting fiberselastomeric fibersPEDOT:PSSpolyurethanestrain sensorswet-spinningScience & TechnologyPhysical SciencesTechnologyChemistry, MultidisciplinaryChemistry, PhysicalNanoscience & NanotechnologyMaterials Science, MultidisciplinaryPhysics, AppliedPhysics, Condensed MatterChemistryScience & Technology - Other TopicsMaterials SciencePhysicsWET-SPINNING PROCESSMECHANICAL-PROPERTIESPOLYMER COMPOSITESCARBON NANOTUBESTHERMOPLASTIC POLYURETHANESMULTIFUNCTIONAL FIBERSPOLYPYRROLE FIBERSPOLYANILINE FIBERSGRAPHENEBEHAVIOR
Licence
Exports
RefWorks
BibTeX
Ref. manager
Endnote
DataCite
NLM
DC