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Structural characterization of novel ionic salts incorporating trihalide anions
journal contributionposted on 01.01.2009, 00:00 authored by P Dean, B Clare, V Armel, Jenny PringleJenny Pringle, C Forsyth, Maria ForsythMaria Forsyth, D MacFarlane
The crystal structures of several low-melting salts containing trihalide ions, namely 1-ethyl-3-methylimidazolium tribromide ([C2mim][Br3]), 1-ethyl-1-methylpyrrolidinium tribromide ([C2mpyr][Br3]), and 1-propyl-1-methylpyrrolidinium triiodide ([C3mpyr][I3]), are reported for the first time. Thermal analysis reveals that the tribromide salts are lower-melting than their monohalide analogues. Analysis of the crystal structures allows examination of the influence of the anions on the physical properties of the salts.