Substituent effects on through-space intervalence charge transfer in cofacial metal-organic frameworks

Doheny, PW; Hua, C; Chan, B; Tuna, F; Collison, D; Kepert, CJ; D'Alessandro, DM

Substituent effects on through-space intervalence charge transfer in cofacial metal-organic frameworks

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posted on 2024-06-13, 14:48 authored by PW Doheny, C Hua, B Chan, F Tuna, D Collison, CJ Kepert, DM D'Alessandro

Using a combined experimental, theoretical and density functional theory analysis, important insights into the effects of structural modifications on the degree of electronic coupling and rate of electron transfer are obtained for the framework [Zn(BPPFTzTz)(tdc)]·2DMF.

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DOI - Is version of https://doi.org/10.1039/d1fd00021g

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England

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English

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http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000671927800001&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=a045e4b2bb1f2b747c68c720ec8913b7

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C1.1 Refereed article in a scholarly journal

Journal

Faraday Discussions

Volume

231

Pagination

152-167

ISSN

1359-6640

eISSN

1364-5498

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0

Publisher

ROYAL SOC CHEMISTRY

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Science & Technology Physical Sciences Chemistry, Physical Chemistry PAIR RADICAL-CATION MIXED-VALENCE IRON COMPLEXES DELOCALIZATION CONDUCTIVITY SPECTROSCOPY EVOLUTION School of Life and Environmental Sciences 3402 Inorganic chemistry 3406 Physical chemistry

Substituent effects on through-space intervalence charge transfer in cofacial metal-organic frameworks

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