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Synthesis and characterisation of rare earth complexes supported by para-substituted Cinnamate Ligands

journal contribution
posted on 01.01.2009, 00:00 authored by G Deacon, Maria ForsythMaria Forsyth, P Junk, S Leary, W Lee
The preparations and characterisations of a range of lanthanoid 4-(R)-substituted (4-Rcinn, R = OH, OMe, NO2, Cl), known to have good anticorrosion properties, are reported. The crystal structure of [Ce(4-OHcinn)3(MeOH)2(H2O)]·MeOH is a polymer, in which the cerium atoms are nonacoordinate, and adjacent cerium atoms are bridged by either two bridging bidentate or two bridging tridentate carboxylate ligands. Each cerium atom also has one monodentate 4-hydroxycinnamate ligand, one aqua ligand, and two methanol ligands.

History

Journal

Zeitschrift für anorganische chemie

Volume

635

Issue

6-7

Pagination

833 - 839

Publisher

Wiley

Location

Leipzig, Germany

ISSN

0044-2313

eISSN

1521-3749

Language

eng

Publication classification

C1.1 Refereed article in a scholarly journal

Copyright notice

2009 Wiley-VCH Verlag GmbH & Co. KGaA