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Synthesis and structure of an ether-bridged double ladder compound: potential in host - guest chemistry

journal contribution
posted on 2003-12-15, 00:00 authored by J Beckmann, Dainis Dakternieks, Andrew DuthieAndrew Duthie, Fong Sheen Kuan, E Tiekink
The synthesis of the first example of an organotin double ladder (6) containing a functional group within the spacer is reported. In the solid state, compound 6 shows an interlaminar cavity whose size and shape suggest the possibility of host–guest chemistry. 119Sn-NMR and ESMS show that compound 6 undergoes extensive dissociation in solution. ESMS of compound 6 to which have been added Li+, Na+, Mg2+ or Cu2+ show only minimal interaction.


History

Journal

Journal of organometallic chemistry

Volume

688

Issue

1-2

Pagination

56 - 61

Publisher

Elsevier BV

Location

Amsterdam, The Netherlands

ISSN

0022-328X

eISSN

1872-8561

Language

eng

Publication classification

C1 Refereed article in a scholarly journal

Copyright notice

2003, Elsevier B.V.