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Synthesis, molecular structure, and isomerisation in solution of (Me3SbS)2Me2SnCl2. Concomitant hypercoordination of tin and antimony

journal contribution
posted on 2003-01-01, 00:00 authored by J Beckmann, Dainis Dakternieks, Andrew DuthieAndrew Duthie, R Foitzik
The reaction of Me3SbCl2 and (Me2SnS)3 afforded the complex (Me3SbS)2Me2SnCl2 in high yields, whose molecular structure features both hypercoordinated tin and antimony atoms. In solution, (Me3SbS)2Me2SnCl2 undergoes a reversible dissociation and ligand interchange reaction to give Me3SbS, Me3SbCl2 and (Me2SnS)3.

History

Journal

Zeitschrift für anorganische und allgemeine chemie

Volume

629

Pagination

1508 - 1510

Publisher

Wiley Interscience

Location

Malden, MA.

ISSN

0044-2313

eISSN

1521-3749

Language

eng

Notes

Published Online: 11 Aug 2003

Publication classification

C1 Refereed article in a scholarly journal

Copyright notice

2003, WILEY-VCH Verlag